منابع مشابه
Oxidation of Pyrite and Marcasite by Thiobacillus ferrooxidans Bacteria
This paper reports results of studies on the influence of the crystallographic mineral structure on the process of pyrite and marcasite leaching. Kinetic studies show that the crystallographic structure of minerals like FeS2 type does not influence the efficiency of the process.
متن کاملFirst-principles electronic structure and relative stability of pyrite and marcasite: Implications for photovoltaic performance
Despite the many advantages (e.g., suitable band gap, exceptional optical absorptivity, earth abundance) of pyrite as a photovoltaic material, its low open-circuit voltage (OCV) has remained the biggest challenge preventing its use in practical devices. Two of the most widely accepted reasons for the cause of the low OCV are (i) Fermi level pinning due to intrinsic surface states that appear as...
متن کاملEvaluating structure selection in the hydrothermal growth of FeS2 pyrite and marcasite
While the ab initio prediction of the properties of solids and their optimization towards new proposed materials is becoming established, little predictive theory exists as to which metastable materials can be made and how, impeding their experimental realization. Here we propose a quasi-thermodynamic framework for predicting the hydrothermal synthetic accessibility of metastable materials and ...
متن کاملEnhanced Photoresponse of FeS2 Films: The Role of Marcasite-Pyrite Phase Junctions.
The beneficial role of marcasite in iron-sulfide-based photo-electrochemical applications is reported for the first time. A spectacular improvement of the photoresponse observed experimentally for mixed pyrite/marcasite-FeS2 films can be ascribed to the presence of p/m phase junctions at the interface. Density functional theory calculations show that the band alignment at the phase boundary con...
متن کاملMarcasite in Black Shales—a Mineral Proxy for Oxygenated Bottom Waters and Intermittent Oxidation of Carbonaceous Muds
Black shales in the geologic record have long been considered to reflect deposition under anoxic or even euxinic conditions. Although bottom-water anoxia favors deposition of black shales, certain biological indicators, such as benthic fossils and bioturbation, suggest that bottom-water conditions may not have been as persistently anoxic as commonly presumed. Examination of twelve marine carbon...
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ژورنال
عنوان ژورنال: Science
سال: 1902
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.15.387.870